大师作文网请问谁有氯代丙二酸二甲酯的msds ,最好是英文的?
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请问谁有氯代丙二酸二甲酯的msds ,最好是英文的?
给你一个Chemwatch版本的 第一部分,第十六部分other information也自己填
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
CHEMWATCH HAZARD RATINGS
Flammability: 1
Toxicity: 0
Body Contact: 4
Reactivity: 1
Chronic: 2
Min/Nil=0
Low=1
Moderate=2
High=3
Extreme=4
NAME CAS RN INT HAZ %
dimethyl chloromalonate
EC NO: 249-275-0 R CODES: R35, R41
•Metal Corrosion Category 1 •Serious Eye Damage Category 1 •Skin Corrosion/Irritation Category 1B 28868-76-0 C >98
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
RISK
Causes severe burns.
Risk of serious damage to eyes.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
■ The material can produce severe chemical burns within the oral cavity and gastrointestinal tract following ingestion.
■ Ingestion of acidic corrosives may produce circumoral burns with a distinct discolouration of the mucous membranes of the mouth, throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may also be evident.
■ The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence.
EYE
■ The material can produce severe chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating.
■ When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more after instillation.
■ Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and burns. Mild burns of the epithelia generally recover rapidly and completely.
■ Irritation of the eyes may produce a heavy secretion of tears (lachrymation).
SKIN
■ The material can produce severe chemical burns following direct contact with the skin.
■ Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with the formation of scar tissue.
■ Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions.
■ Open cuts, abraded or irritated skin should not be exposed to this material.
■ Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
INHALED
■ Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first removing or neutralising the irritant and then repairing the damage.
■ Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous membrane damage. Symptoms of exposure may include dizziness, headache, nausea and weakness.
■ Inhalation hazard is increased at higher temperatures.
■ The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This is because of the lack of corroborating animal or human evidence.
■ Inhalation of quantities of liquid mist may be extremely hazardous, even lethal due to spasm, extreme irritation of larynx and bronchi, chemical pneumonitis and pulmonary oedema.
CHRONIC HEALTH EFFECTS
■ Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic problems.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.
Section 4 - FIRST AID MEASURES
SWALLOWED
* For advice, contact a Poisons Information Centre or a doctor at once.
* Urgent hospital treatment is likely to be needed.
* If swallowed do NOT induce vomiting.
* If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
EYE
If this product comes in contact with the eyes:
* Immediately hold eyelids apart and flush the eye continuously with running water.
* Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
* Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
* Transport to hospital or doctor without delay.
SKIN
If skin or hair contact occurs:
* Immediately flush body and clothes with large amounts of water, using safety shower if available.
* Quickly remove all contaminated clothing, including footwear.
* Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
* Transport to hospital, or doctor.
INHALED
* If fumes or combustion products are inhaled remove from contaminated area.
* Lay patient down. Keep warm and rested.
* Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
* Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
* Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.
* Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).
* As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested.
* Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered.
NOTES TO PHYSICIAN
■ Treat symptomatically.
For acute or short term repeated exposures to strong acids:
* Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.
* Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling
* Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.
* Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in specific tissues.
Section 2 - COMPOSITION / INFORMATION ON INGREDIENTS
CHEMWATCH HAZARD RATINGS
Flammability: 1
Toxicity: 0
Body Contact: 4
Reactivity: 1
Chronic: 2
Min/Nil=0
Low=1
Moderate=2
High=3
Extreme=4
NAME CAS RN INT HAZ %
dimethyl chloromalonate
EC NO: 249-275-0 R CODES: R35, R41
•Metal Corrosion Category 1 •Serious Eye Damage Category 1 •Skin Corrosion/Irritation Category 1B 28868-76-0 C >98
Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
RISK
Causes severe burns.
Risk of serious damage to eyes.
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
■ The material can produce severe chemical burns within the oral cavity and gastrointestinal tract following ingestion.
■ Ingestion of acidic corrosives may produce circumoral burns with a distinct discolouration of the mucous membranes of the mouth, throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may also be evident.
■ The material has NOT been classified by EC Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence.
EYE
■ The material can produce severe chemical burns to the eye following direct contact. Vapours or mists may be extremely irritating.
■ When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more after instillation.
■ Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and burns. Mild burns of the epithelia generally recover rapidly and completely.
■ Irritation of the eyes may produce a heavy secretion of tears (lachrymation).
SKIN
■ The material can produce severe chemical burns following direct contact with the skin.
■ Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may heal slowly with the formation of scar tissue.
■ Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions.
■ Open cuts, abraded or irritated skin should not be exposed to this material.
■ Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected.
INHALED
■ Evidence shows, or practical experience predicts, that the material produces irritation of the respiratory system, in a substantial number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first removing or neutralising the irritant and then repairing the damage.
■ Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous membrane damage. Symptoms of exposure may include dizziness, headache, nausea and weakness.
■ Inhalation hazard is increased at higher temperatures.
■ The material has NOT been classified by EC Directives or other classification systems as "harmful by inhalation". This is because of the lack of corroborating animal or human evidence.
■ Inhalation of quantities of liquid mist may be extremely hazardous, even lethal due to spasm, extreme irritation of larynx and bronchi, chemical pneumonitis and pulmonary oedema.
CHRONIC HEALTH EFFECTS
■ Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.
Long-term exposure to respiratory irritants may result in disease of the airways involving difficult breathing and related systemic problems.
Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.
Section 4 - FIRST AID MEASURES
SWALLOWED
* For advice, contact a Poisons Information Centre or a doctor at once.
* Urgent hospital treatment is likely to be needed.
* If swallowed do NOT induce vomiting.
* If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
EYE
If this product comes in contact with the eyes:
* Immediately hold eyelids apart and flush the eye continuously with running water.
* Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.
* Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.
* Transport to hospital or doctor without delay.
SKIN
If skin or hair contact occurs:
* Immediately flush body and clothes with large amounts of water, using safety shower if available.
* Quickly remove all contaminated clothing, including footwear.
* Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.
* Transport to hospital, or doctor.
INHALED
* If fumes or combustion products are inhaled remove from contaminated area.
* Lay patient down. Keep warm and rested.
* Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.
* Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.
* Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.
* Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).
* As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical observation even if no symptoms are (yet) manifested.
* Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered.
NOTES TO PHYSICIAN
■ Treat symptomatically.
For acute or short term repeated exposures to strong acids:
* Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.
* Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling
* Intravenous lines should be established immediately in all cases where there is evidence of circulatory compromise.
* Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins in specific tissues.